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The interplay between configurational entropy and the enthalpy of ordered structures governs phase stability in compositionally complex alloys. In the refractory alloy Re0.6(NbTiZrHf)0.4, this balance is particularly delicate: pressure stabilizes a disordered body-centred-cubic (bcc) solid solution over the ambient hexagonal Laves phase via a martensitic route. Using in situ laser heating with synchrotron X-ray diffraction in a diamond-anvil cell, we demonstrate that the metastable bcc phase can be controllably transformed into a large-scale 2×2×2 B2-type superstructure with primitive-cubic symmetry (Pm3 ̅m). This long-period ordered phase is crystallographically distinct from conventional B2 ordering in multicomponent alloys, establishing a pathway to achieve chemical ordering from pressure-stabilized solid solutions. More broadly, these findings demonstrate that combining compression with subsequent thermal activation can unlock recoverable three-dimensional superstructures, offering new opportunities to tailor strength, transport properties, and stability in compositionally complex alloys. 

At ambient conditions, the high-entropy alloy superconductor R⁢e0.6⁢(NbTiZrHf)0.4 exhibits exceptional mechanical properties among high-entropy alloys, with its hexagonal phase achieving nanoindentation hardness of 18.5 GPa. We report on a unique pressure-induced structural transformation from a hexagonal phase to a body-centered cubic (BCC) phase, revealed by synchrotron x-ray diffraction measurements up to 70 GPa. This first-order transition, accompanied by a 6.1% volume collapse, occurs at 44 GPa and results in a BCC structure with random site occupancy by the five constituent elements, which is remarkably retained upon decompression to ambient conditions. The transformation proceeds via a martensiticlike, diffusionless mechanism without elemental segregation, enabled by pressure-induced electronic redistribution and atomic-scale disorder. These findings demonstrate a rare case of metastable phase retention in a chemically complex alloy and offer new insights into structure-stability relationships under pressure. 

We present scanning electrochemical cell microscopy (SECCM) studies of Ag nucleation and growth on carbon and indium tin oxide (ITO) electrodes. 

Molecular case studies (MCSs) provide educational opportunities to explore biomolecular structure and function using data from public bioinformatics resources. The conceptual basis for the design of MCSs has yet to be fully discussed in the literature, so we present molecular storytelling as a conceptual framework for teaching with case studies. Whether the case study aims to understand the biology of a specific disease and design its treatments or track the evolution of a biosynthetic pathway, vast amounts of structural and functional data, freely available in public bioinformatics resources, can facilitate rich explorations in atomic detail. To help biology and chemistry educators use these resources for instruction, a community of scholars collaborated to create the Molecular CaseNet. This community uses storytelling to explore biomolecular structure and function while teaching biology and chemistry. In this article, we define the structure of an MCS and present an example. Then, we articulate the evolution of a conceptual framework for developing and using MCSs. Finally, we related our framework to the development of technological, pedagogical, and content knowledge (TPCK) for educators in the Molecular CaseNet. The report conceptualizes an interdisciplinary framework for teaching about the molecular world and informs lesson design and education research. 

Synopsis Paleozoic skies were ruled by extinct odonatopteran insects called “griffenflies,” some with wingspans 3 times that of the largest extant dragonflies and 10 times that of common extant dragonflies. Previous studies suggested that flight was possible for larger fliers because of higher atmospheric oxygen levels, which would have increased air density. We use actuator disk theory to evaluate this hypothesis. Actuator disk theory gives similar estimates of induced power as have been estimated for micro-air vehicles based on insect flight. We calculate that for a given mass of griffenfly, and assuming isometry, a higher density atmosphere would only have reduced the induced power required to hover by 11%, which would have supported a flyer 3% larger in linear dimensions. Steady-level forward flight would have further reduced induced power but could only account for a flier 5% larger in linear dimensions. Further accounting for the higher power available due to high-oxygen air and assuming isometry, we calculate that the largest flyer hovering would have been only 1.19 times longer than extant dragonflies. We also consider known allometry in dragonflies and estimated allometry in extinct griffenflies. But such allometry only increases flyer size to 1.22 times longer while hovering. We also consider profile and parasite power, but both would have been higher in denser air and thus would not have enhanced the flyability of larger griffenflies. The largest meganeurid griffenflies might have adjusted flight behaviors to reduce power required. Alternatively, the scaling of flight muscle power may have been sufficient to support the power demands of large griffenflies. In literature estimates, mass-specific power output scales as mass0.24 in extant dragonflies. We need only more conservatively assume that mass-specific muscle power scales with mass0, when combined with higher oxygen concentrations and induced power reductions in higher-density air to explain griffenflies 3.4 times larger than extant odonates. Experimental measurement of flight muscle power scaling in odonates is necessary to test this hypothesis. 

Two-dimensional semiconductors (2DSCs) are attractive materials for a variety of applications in electronics, photovoltaics, and catalysis. Despite their promise, it is often unclear how the performance of 2DSCs is influenced by structural defects present in these materials such as atomic vacancies or step-edges. A better fundamental understanding of how such structural features influence the generation and transport of charge carriers in 2DSCs will be critical in the pursuit of improved practical devices moving forward. In this Opinion, we highlight how electrochemistry can be leveraged to reveal fascinating insights into the behavior of 2DSCs. Recent advancements in techniques for mapping the rate of photoelectrochemical processes at 2DSCs are outlined and salient experiments employing these techniques are discussed. We conclude with sharing our perspective on opportunities within this field moving forward. 

Abstract Identification and follow-up observations of the host galaxies of fast radio bursts (FRBs) not only help us understand the environments in which the FRB progenitors reside, but also provide a unique way of probing the cosmological parameters using the dispersion measures (DMs) of FRBs and distances to their origin. A fundamental requirement is an accurate distance measurement to the FRB host galaxy, but for some sources viewed through the Galactic plane, optical/near-infrared spectroscopic redshifts are extremely difficult to obtain due to dust extinction. Here we report the first radio-based spectroscopic redshift measurement for an FRB host galaxy, through detection of its neutral hydrogen (Hi) 21 cm emission using MeerKAT observations. We obtain an Hi–based redshift ofz= 0.0357 ± 0.0001 for the host galaxy of FRB 20230718A, an apparently nonrepeating FRB detected in the Commensal Real-time ASKAP Fast Transients survey and localized at a Galactic latitude of –0.°367. Our observations also reveal that the FRB host galaxy is interacting with a nearby companion, which is evident from the detection of an Hibridge connecting the two galaxies. A subsequent optical spectroscopic observation confirmed an FRB host galaxy redshift of 0.0359 ± 0.0004. This result demonstrates the value of Hito obtain redshifts of FRBs at low Galactic latitudes and redshifts. Such nearby FRBs whose DMs are dominated by the Milky Way can be used to characterize these components and thus better calibrate the remaining cosmological contribution to dispersion for more distant FRBs that provide a strong lever arm to examine the Macquart relation between cosmological DM and redshift. 

ABSTRACT Localization of fast radio bursts (FRBs) to arcsecond and subarcsecond precision maximizes their potential as cosmological probes. To that end, FRB detection instruments are deploying triggered complex-voltage capture systems to localize FRBs, identify their host galaxy, and measure a redshift. Here, we report the discovery and localization of two FRBs (20220717A and 20220905A) that were captured by the transient buffer system deployed by the MeerTRAP instrument at the MeerKAT telescope in South Africa. We were able to localize the FRBs to precision of $$\sim$$1 arcsecond that allowed us to unambiguously identify the host galaxy for FRB 20220717A (posterior probability $$\sim$$0.97). FRB 20220905A lies in a crowded region of the sky with a tentative identification of a host galaxy but the faintness and the difficulty in obtaining an optical spectrum preclude a conclusive association. The bursts show low linear polarization fractions (10–17 per cent) that conform to the large diversity in the polarization fraction observed in apparently non-repeating FRBs akin to single pulses from neutron stars. We also show that the host galaxy of FRB 20220717A contributes roughly 15 per cent of the total dispersion measure (DM), indicating that it is located in a plasma-rich part of the host galaxy which can explain the large rotation measure. The scattering in FRB 20220717A can be mostly attributed to the host galaxy and the intervening medium and is consistent with what is seen in the wider FRB population.